Wheel Alignment is to adjust and align the wheels of your car for them to be at proper contact with the road and at proper angles with each other. A quality wheel alignment is mandatory for even tread wear and proper handling.
Wheel balancing, also known as tire balancing, is the process of equalizing the weight of the combined tire and wheel assembly so that it spins smoothly at high speed. Balancing involves putting the wheel/tire assembly on a balancer, which centers the wheel and spins it to determine where the weights should go.
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This basic nature of nitrogen is that it’s cooler than compressed air and a cooler tyre means that the stress levels on the tyre while moving are lesser. The tread wear and tear is also lesser due to the lesser temperature.